Freezing point of pure water Tfo=0∘ C
Freezing point of ethylene glycol solution Tf=−24∘ C
Depression in freezing point, Δ Tf=Tfo−Tf=0∘ C−(−24∘ C)=24∘ C
Value of difference of two temperatures is same in ∘ C and K , thus
Δ Tf=24∘ C or 24 K
Δ Tf=i × m × kf
Assuming glycol to be undissociated in water, i=1
24=1 × m × 1.86
m=1.8624
M glycol × W water (in kg) W glycol =1.8624
62 × 18.6W glycol =1.8624 W_glycol =14880 g=14.88 kg