To find the degree of ionization
, we need to use the boiling point elevation formula and the van't Hoff factor. The formulas we will use are:
ΔTb=i⋅Kb⋅m
where:
is the boiling point elevation,
is the van't Hoff factor,
is the molal boiling point elevation constant, and
is the molality of the solution.
Given data:
ΔTb=100.52∘C−100∘C=0.52∘C
- Mass of = 10 g
- Mass of water = 100 g = 0.1 kg
- Molar mass of = 200 g/mol
- = 0.52 K kg mol-1
First, we calculate the molality (m):
m=mass of solvent in kgmoles of solute
=0.120010mol kg−1
=0.5mol kg−1
Next, using the formula for boiling point elevation:
0.52=i⋅0.52⋅0.5
i=0.52⋅0.50.52
i=0.51
Now, the van't Hoff factor i is related to the degree of ionization
. For the electrolyte
, which ionizes as
AB2→A2++2B− , the van't Hoff factor
i can be expressed as:
i=1+(n−1)α
where
- is the number of ions produced (which is 3 for
AB2→A2++2B− )
- is the degree of ionization
Substituting i=2 into the equation:
2=1+2α
2−1=2α
α=21
The degree of ionization
is therefore
0.5×10−1=5×10−2 .
Hence, the degree of ionization of the electrolyte
is approximately 5
(the nearest integer is 5).