Exam
Chemistry
Number of ambidentate ligands among the following is _________.
NO2−,SCN−,C2O42−,NH3,CN−,SO42−,H2O.
Correct Answer:
3
Explanation
Ambidentate ligands are ligands that can attach to a central metal atom through two different atoms. Let’s analyze the given ligands one by one:
- NO2−: This ligand can bind through either the nitrogen (N) or the oxygen (O). Therefore,NO2−is an ambidentate ligand.
- SCN−: This ligand can bind through either the sulfur (S) or the nitrogen (N). Therefore,SCN−is an ambidentate ligand.
- C2O42−(oxalate): This is a bidentate ligand, but it coordinates through both oxygen atoms only. Therefore, it is not an ambidentate ligand.
- NH3: This ligand can only bind through nitrogen (N). Therefore, it is not an ambidentate ligand.
- CN−: This ligand can bind through either carbon (C) or nitrogen (N). Therefore,CN−is an ambidentate ligand.
- SO42−(sulfate): This ligand typically coordinates through oxygen atoms. It is not considered an ambidentate ligand.
- H2O: This ligand can only bind through oxygen (O). Therefore, it is not an ambidentate ligand.
Based on this analysis, the ambidentate ligands are
NO2−
, SCN−
, and CN−
.
Therefore, the number of ambidentate ligands among the given options is 3.
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