Aqueous tension at 287 K = 14 mm of Hg.
Hence actual pressure = (758 – 14)
= 744 mm of Hg.
Moles of N2 = 760( 758 − 14 ) × 0.0821 × 28730 × 10 − 3
= 1.246 × 10 − 3 mol
mass of N2 = 1.246 × 10 − 3 × 28
mass % of N2 = totalmassmassof′N′ × 100
= 0.1841.246 × 28 × 10 − 3 × 100
= 0.184124.6 × 28 % = 18.96%
≃ 19%