Virat Batch 2027
Champion Batch 2028
Divine JEE 1-on-1
Consider the cell
Pt(s)∣H2( g,1 atm)∣H+(aq,1M)∣∣Fe3+(aq),Fe2+(aq)∣Pt(s)\mathrm{Pt}_{(\mathrm{s})}\left|\mathrm{H}_{2}(\mathrm{~g}, 1 \mathrm{~atm})\right| \mathrm{H}^{+}(\mathrm{aq}, 1 \mathrm{M})|| \mathrm{Fe}^{3+}(\mathrm{aq}), \mathrm{Fe}^{2+}(\mathrm{aq}) \mid \operatorname{Pt}(\mathrm{s})Pt(s)∣H2( g,1 atm)∣H+(aq,1M)∣∣Fe3+(aq),Fe2+(aq)∣Pt(s)
When the potential of the cell is 0.712 V0.712 \mathrm{~V}0.712 V at 298 K298 \mathrm{~K}298 K, the ratio [Fe2+]/[Fe3+]\left[\mathrm{Fe}^{2+}\right] /\left[\mathrm{Fe}^{3+}\right][Fe2+]/[Fe3+] is _____________. (Nearest integer)
Given : Fe3++e−=Fe2+,EθFe3+,Fe2+∣Pt=0.771\mathrm{Fe}^{3+}+\mathrm{e}^{-}=\mathrm{Fe}^{2+}, \mathrm{E}^{\theta} \mathrm{Fe}^{3+}, \mathrm{Fe}^{2+} \mid \mathrm{Pt}=0.771Fe3++e−=Fe2+,EθFe3+,Fe2+∣Pt=0.771
2.303RTF=0.06 V \frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.06 \mathrm{~V} F2.303RT=0.06 V
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