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At 310 K310 \mathrm{~K}310 K, the solubility of CaF2\mathrm{CaF}_{2}CaF2 in water is 2.34×10−3 g/100 mL2.34 \times 10^{-3} \mathrm{~g} / 100 \mathrm{~mL}2.34×10−3 g/100 mL. The solubility product of CaF2\mathrm{CaF}_{2}CaF2 is ____________ ×10−8( mol/L)3\times 10^{-8}(\mathrm{~mol} / \mathrm{L})^{3}×10−8( mol/L)3. (Give molar mass : CaF2=78 g mol−1\mathrm{CaF}_{2}=78 \mathrm{~g} \mathrm{~mol}^{-1}CaF2=78 g mol−1)
CaF2 ⇌s Ca2+ s+2 F−2 s\mathrm{CaF}_{2} \stackrel{\mathrm{s}}{\rightleftharpoons} \underset{ \mathrm{s}}{\mathrm{Ca}^{2+}}+\underset{2 \mathrm{~s}}{2 \mathrm{~F}^{-}}CaF2 ⇌s sCa2++2 s2 F−
Ksp =s(2 s)2 =4 s3 \begin{aligned} \mathrm{K}_{\mathrm{sp}} &=\mathrm{s}(2 \mathrm{~s})^{2} \\\\ &=4 \mathrm{~s}^{3} \end{aligned} Ksp =s(2 s)2 =4 s3
Solubility (s)=2.34 × 10−3 g / 100 mL(\mathrm{s})=2.34 \times 10^{-3} \mathrm{~g} / 100 \mathrm{~mL}(s)=2.34 × 10−3 g / 100 mL
=2 ⋅ 34 × 10−3 × 1078=\frac{2 \cdot 34 \times 10^{-3} \times 10}{78}=782 ⋅ 34 × 10−3 × 10 mole /// lit
=3 × 10−4 mole / lit=3 \times 10^{-4} \mathrm{~mole} / \mathrm{lit}=3 × 10−4 mole / lit
∴ Ksp=4 ×(3 × 10−4)3\therefore \mathrm{K}_{\mathrm{sp}}=4 \times\left(3 \times 10^{-4}\right)^{3}∴ Ksp=4 ×(3 × 10−4)3
=108 × 10−12 =0.0108 × 10−8( mole / lit)3 \begin{aligned} &=108 \times 10^{-12} \\\\ &=0.0108 \times 10^{-8}(\mathrm{~mole} / \mathrm{lit})^{3} \end{aligned} =108 × 10−12 =0.0108 × 10−8( mole / lit)3
∴ x ≈ 0 \begin{aligned} & \therefore x \approx 0 \end{aligned} ∴ x ≈ 0
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